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a, b ) Volcano plot of a ) serum and b ) subcutaneous adipose tissue (SFAT) metabolites identified by LC-MS/MS in Cth / mice after 6 days of CTRL or CysF diet (n = 4 CTRL and n = 5 CysF for serum, n = 6/group for SFAT)

Alternatively, due to its strong electrophilicity, FA might react with other abundant cellular thiols such as free cysteine 45 and with sulfhydryl groups present in proteins involved in redox control, thus also contributing to cellular redox disruption

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Wawilow, 1927) with Kashas rule emphasizing that the emitting level of a given multiplicity is the lowest excited level of that multiplicity (Kasha, 1950) gives rise to an important principle that the shape of the fluorescence spectrum is independent of the excitation wavelength